Bis(2,2′-bipyridine N,N′-dioxide)bis(tricyanomethanido)manganese(II)
نویسندگان
چکیده
In the title complex, [Mn(C(4)N(3))(2)(C(10)H(8)N(2)O(2))(2)], the Mn(II) atom lies on an inversion center and is coordinated by two 2,2'-bipyridine N,N'-dioxide (dpdo) mol-ecules and two tricyano-methanide (tcm) ligands to form a distorted octa-hedral geometry. Weak inter-molecular C-H⋯O or C-H⋯N hydrogen bonds, involving either the O atom of the dpdo mol-ecule and the pyridyl H atom, or the N atom of the tcm anion and the pyridyl H atom, result in the formation of a three-dimensional network structure.
منابع مشابه
μ-Oxalato-bis[bis(2,2′-bipyridine)manganese(II)] bis(perchlorate) 2,2′-bipyridine solvate
The unit cell of the title compound, [Mn(2)(C(2)O(4))(C(10)H(8)N(2))(4)](ClO(4))(2)·C(10)H(8)N(2), consists of a binuclear cation, two perchlor-ate anions, and one solvent 2,2'-bipyridine (bpy) mol-ecule. In the complex cation [Mn(2)(C(2)O(4))(C(10)N(2)H(8))(4)](2+), two Mn(II) atoms are bridged by a bis-(bidentate) oxalate ligand, each Mn(II) atom being further coordinated by two bpy ligands i...
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